Yes; sites with Apple Pay get purchases from me almost instantly.
It's a good way to battle people otherwise preferring to use a platform they already have an account on (e.g. eBay; Amazon) where you lose more on commission.
Amazon operates a payment service, and eBay used to. Using Amazon to pay doesn't mean you're buying something on amazon.com, just as using PayPal to pay doesn't mean you're buying something on ebay.com .